Restek Technical Note #59889 DJVu file 24 page 850k

Definition of Chirality and Chiral Chromatography
Chiral Columns offer Unique Selectivity

 Rt-bDEXsm provides best chiral separation of

  • isoborneol and a-terpineol
  • complete separation of a-ionone
  • Cis and tran linalool oxide enantiomers

Rt-bDEXse

  • resolves optical isomers of ethyl-2-methylbutyrate, styrene oxide and camphor with some overlap
  • linalool and linalyl acetate enantiomers
  • Rt-bDEXsp methol enantiomers
  • Rt-bDEXsa
  • 1-octen-3-ol and carvone
  • b-citronellol
  • racemic cis and trans rose oxides

Rt-bDEXcst

  • all the 10 irone isomers
  • max resolution of gamma(5) and delta-lactones(7) +-
    Rt-bDEXsm
  • optimum for sepration of (+-) a and b-pinene, limonene and menthone in peppermint oil and spearmint oil

Rt-bDEXsa

  • best for optical isomer of carvone
  • resolves limonent enantiomers

Optimisation of Chiral Separations
Chiral Specific Applications of Essential Oils, Flavors and Pharmaceuticals

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A Guide to the Analysis of Chiral Compounds #59889

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